Margaritone d'Arezzo (di Magnano): Madonna and Child Enthroned (ca.1270) Pre-Rennaisance.
Sienese School Painting of Saint Agnes. Saint Agnes was not green originally. The tempera paint was applied in layers to get the correct skintone. The green showing is a result of the original colors being worn off with time.
koredzas: “ Duccio di Buoninsegna - Madonna and Child. 1290–1300 ”